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That as well as what flyman said is basically what it all boils down to for me. If it comes straight from the earth how can it be bad? (and yes I am aware there ARE some posinous plants and what not but I would rather take my risk with them then with some crazy compound)
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Those very same "crazy compounds" are found your precious earth food too. What do you think gets you high in marijuana? Magic?
Second, "crazy compounds" are able to receive much more attention and safety testing than plants, which may contain dozens of psychoative chemicals.