For a man, in most situations sex is something you earn with honesty, confidence, and effort. I've never liked situations where I just fall into sex with women, I like to pursue so that I know that I've demonstrated through effort that I've earned her affections. I've found most women like this, too.
I suspect you might have been missing one or more of the ingredients, because she didn't seem interested. I can't really blame her, she just met you. It's hard to gain trust or form more than just a basic physical attraction in one night, especially considering that from your description she wasn't really in the mood.
My advice is this: be honest, be as confident as you're comfortable with, and make an honest effort to woo. And don't expect women to sleep with you right after meeting you.
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