Giving someone their first joint can be a very special occasion... As long as you can control their experience in some way, i.e. provide the weed (and guarentee the quality) and more importantly (especialy for the girls) provide a nice, safe place to smoke. Your surroundings can have as much an effect on the high as the quality of the smoke. Paranoia is a common side effect and can really turn a first time smoker off.
Chances are she probably didn't inhale properly (which will just take a little practice) and also she might not have felt particulaly comfortable trying to smoke with a bunch of guys giggling at her.
If you are introducing someone to weed... be nice to them! If they have a bad time with it the worst possible outcome is that it could taint your friendship.
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