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The song is called "Goodbye Horses" by Q Lazzarus.
As NoSoup indicated, the scene is a parody of the scene in "Silence of the Lambs" in which Buffalo Bill puts on make up, his skin suit and does the tuck, seductively asking, "Would you fuck me? I'd fuck me."
And yes, I have see "Silence of the Lambs" way too many times.
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