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Nicotine is known to be a muscle relaxant. In fact, my twitchy and paranoid friend often eats a banana after smoking a cigarette to not have to go to the bathroom because bananas have constipants (or so he says).
So it is possible that with so much smoking, your blood vessels down there had been dilated to the point of not holding as much blood anymore.
However, so many people get soft before the 1st time, it is probably that. All those years of wanting it so bad make you doubt that you'll be able to fulfill your expectations, and *flop*.
Don't worry, it's no big deal. Take it easy. Don't think about your dick as you try and have sex, but rather about her, or focus on what turns you on about her...you'll be fine.
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