Cats will occasionally have pee "accidents". Poop is generally a communication of some sort. Did you tick her off yesterday? Was the box clean? Anything out of the ordinary happen?
There's an enzymatic cleaner product called Nature's Miracle that does amazing things with pet stains (and other organic stains, for that matter). You totally saturate the stain with the material, and it enzymes the stain right out. Miraculous! You can get it at most any pet store.
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