I think that might have something to do with the color palette, there are only a limited amount of colors in a .gif (256 I think?) so that blue might be the closest thing to orange? I'm not certain though. When you save the .gif there should be an option for quality versus file size so the higher the quality the more colors you have available. At really low quality you'll only have a few colors and it'll choose the closest one. But I'm not certain this is the problem since you said it shows up wrong in IE. What about in Firefox or in Windows picture viewer?
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