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The only way to do that truely would be to format your drive, set up the partitions as you want them, then reinstall.
Software such as Partition Magic to do this as well.
With XP you can do some manipulation and have the other 65 gigs show up in a folder on your C drive, but that isn't any better for your situation.
You could also just leave the drive the way it is and use the d drive for storing all your other stuff. Other programs you install and data files and leave the C drive for just your OS.
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