Some DVDs will fit on a single DVDR. For example, most classic films will work (their lack of any special featuers is actually a good thing for a once).
A neat trick I've learned is checking IMDB, under the 'dvd details' page. If the DVD format is 'SS-SL' then it will usually fit on a single DVDR. If it is 'SS-RSDL' or something else, then you'll need multiple DVDRs. SS-SL is single layered (DVD-5). As far as I know, SS-RSDL is DVD-9. Anyway IMDB is a nice way to figure it out ahead of time.
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