Nothing's wrong. Every woman is different and not all women are multi-orgasmic. Some women get a refractory period the same way many men do. I know for me at least after I've had a really big orgasm I can get VERY uncomfortable physically if we keep having sex. It does't happen all the time - depends on a number of things like health and time of the month and things like that - but when it does happen, it's an "OK, I'm done now could you please please hurry it up?" kind of thing.
She seems open-minded enough, see if she'd like to keep going once and figure out if it's a physical thing, or if she's just lacking an experience that would have her keep going.
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"If ten million people believe a foolish thing, it is still a foolish thing."
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