Like charliex said, you will need to Edit the boot.ini file on the root of C. (The start/control panel.... edit option is not available in 2000, at least not on the server.)
Under the [ operating systems ] heading find the line for the OS you want to get rid of. Write it down exactly in case you delete the wrong one. After you have it written down, delete it. Save the file, then reboot. This should do it.
BTW, I'm a bit confused as there is no Windows 2000 Family version, only Pro and server. Is your friend referring to WinME?
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