It's simple, but the second solo in Comfortably Numb sends a chill up my spine every time.
Other votes:
The start of Heart's Crazy on You
Stairway to Heaven. Naturally.
Gotta second the votes for November Rain, Sultans of Swing and Eruption
Hotel California
Layla. By Cream, not the Unplugged version
Bohemian Rhapsody. Again, simple, but still great
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Strewth
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