If you are just interested in distilling small quantities, then a stovetop distiller might be your best bet. You can find them online for distilling 'water' and they will usually handle about a half gallon or so at a time.
Oh, the the poisioning of self-distilled beverages is a moonshiners problem related to wood-alcohols contaminating the stuff they are distilling. If you are just distilling wine, it should be perfectly safe, as long as you use good equipment. Although it is probably illegal.
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