There are really too many for me to name... but personally I think that the craziest solos come out of...
-Zakk Wylde
-Kirk Hammett
-Tony Iommi
-Eddie Van Halen
Those four, are, to me, in a league of their own as far as soloing goes. As for more general guitarists, these guys also come to mind...
-Billy Corgan (VERY underrated)
-Jack White (VERY VERY VERY VERY Underrated... sure, the White Stripes may seem like all power chords to most, but you have to see him play solos with a slide in person to really get a feel for how talented he is... also, he can sing and play rather techical stuff at the same time, which is REALLY hard... for non-guitarists, think rubbing your stomach and patting your head at the same time... times 80,000,000,000.)
-Frank Zappa (He's just plain awesome)
-Steve Gaines
-James Hetfield
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