I can't really think of any freeweight exercises that isolate the latissimus dorsi specifically.
Besides the exercise listed in the above posts. I like to lie on my back on bench (lengthwise) and hold two dumbells or a barbell (light weights) directly above me.
Then, I slowly (with the arms straight) bring them behind my head and parallel to the floor. Then reverse the motion until the weights are back above you.
Maybe it's doing the infraspitus. Not sure since I usually do this at the end of the back and shoulder exercises.
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