To me it's the simple, mellow neck/middle sound of David Gilmour on 'Shine On You Crazy Diamond.' So rich and slow - it's like a guitar milkshake.
As for cool 'hair on the back of your neck' distorted sounds - anything with a well set-up flanger that is not being used to hide the sins of the player does it for me. "Spirit of Radio" (Rush/Alex Lifeson) is one example that comes to mind.
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