Callipygian is a good one.
Crapulent - suffering the consequences of overindulgence in food and or drink.
Defenestrate - To throw out of a window.
Mellifluous
Onomatopoeia
Zarf (a metal or ceramic holder for a glass or paper drinking vessal for a hot beverage. From Turkish.)
Aglet - the tape around each end of a shoelace.
My favortie words based on meaning, though, are:
Pentasyllabic, because it is, and
Hipposesquipedalian, for the same reason.
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Light a man a fire, and he will be warm while it burns.
Set a man on fire, and he will be warm for the rest of his life.
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