I'm a straight woman, although I state that with some hesitation. I have been sexually attracted to a couple of women in my life. I've never had sex with a woman, but if a friendship had developed with these woman (in the past) I think it could have turned sexual if the attraction was mutual.
I'm not sure about the ethics issue, with regards to tempting someone to switch teams. If you're friends with this person, and express your attraction to her, I can't see how she would find it offensive. She may find your honesty endearing, even if she didn't feel the same way about you. If your hit on a woman, just because you know she's a lesbian and think it would be hot to fuck her, then you're a jerk.
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