I can't imagine a reason that wouldn't work. However, I wouldn't ever do it that way. You're just having to double boot your system every time you want to change operating systems then...once to reconfig boot parameters in your bios, and once to have it take effect.
What boot loader are you using that won't do what you're looking for? Although a bit touchy, you can manually configure Grub to do damn near anything I can imagine.
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Don't mind me. I'm just releasing the insanity pressure from my headvalves.
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