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Call animal control. Seriously.
If you see babies, (they come out during the day, too) and they are small and just learning to walk around, you can pick them up by their tails. I've done this, it's pretty funny. They're all hair and no glands yet. Doesn't do any good if momma is still around, though.
If the skunks are now gone but kitties are present, catching them with a live trap (I can walk you through that, just did with another guy on another site literally 10 minutes ago) and taking them to a local shelter or rescue is the best option. I trapped cats for years and helped my wife found a rescue group at a university we used to attend, so I've got plenty of trapping experience under my belt.
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We contend that for a nation to try to tax itself into prosperity is like a man standing in a bucket and trying to lift himself up by the handle.
-Winston Churchill
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