The boot menu can be accessed in the control panel, under
System/Advanced/Startup and Recovery/System Startup/Edit
Once you delete the part of the boot menu dedicated to your new XP install you can delete the windows folder from that installation.
I'm not sure how to remove the new user, but you can make it so the administrator account logs on automatically and you never see the other account. Go to the Run button on the start menu and type the following:
"control userpasswords2" without the quotes
Then highlight the admin account and uncheck "Users must enter a user name or password to use this computer"
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