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If you haven't formatted your drive into an NT File System (NTFS) it should work fine... If you have done that then I honestly don't know.
Most externals now a days are formatted as FAT32 which is compatible with both
Looking at my manual for my external (Western Digital 500GB My Book), it is perfectly compatible with Windows 2000/XP/Vista and Mac OS X 10.2.8 or later. I have never had problems between Doze and a Mac-attack.
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