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My guess is that it spoiled on you. What you were probablly smelling was ammonia, lots of foods that rot will begin to give off naturally occurring ammonia as a by-broduct of the decomposers doing their job. Although I have not specifically heard of coconuts doing this, I think its a good guess.
If you still smell it on a fresh one, then it may just be your sniffer. Coconuts do have a rather strong/distinctive odor, and your brain may just be crossing its signals.
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If you have any poo... fling it NOW!
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