You can get a yeast infection or a UTI when you first start having sex - or with a change in partners. If this happens after you have sex, each time, then I would lean towards latex issue not yeast infection. Sex when you have a yeast infection is painful. Non-oxyl-nine (did I spell that right?) - the spermicide can also cause issues.
Try polyurethane condoms like Trojan Supra - that would be the easiest way to see if you are having problems with latex condoms.
Regardless, if you are having issues and just became sexually active you need to see a doc.
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