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Vinigar has always seemed to work well for me. Soak the clothes in a solution of vinigar 50/50 or when the collar rings are really bad I have used straight vinigar. I've soaked it overnight usually. Then wash as usual. Oxyclean also does seem to go a very good job on general stains. When I have a more dirty load that I'm washing and I don't want to pre-treat everything I just throw in some Oxyclean with my detergent (dunno if your supposed to do that - can't remember what the instructions said) and wash them. I'll check a few and if they're not satisfactorily clean I'll do them once more in it. That's usually enough to get the stains out though.
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"Always learn the rules so that you can break them properly." Dalai Lama
My Karma just ran over your Dogma. 
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