Ubuntu. I've been trying Linux on the desktop for several years now, but never have I found a distro that "just works" as much as Ubuntu does. And it still retains the power of a Debian system.
Projects such as Automatix for Ubuntu will also setup and install all the programs, codecs, etc, that you need to make a good desktop. It's a lifesaver.
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"Good people do not need laws to tell them to act responsibly, while bad people will find a way around the laws."
--Plato
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