Your best bet is to contact the catholic church. I'm not catholic, but I've donated through them a dozen times to places all over the world, and I wasn't worried about them keeping a ridiculous overhead. Your local church should be able to put you in contact with the internationa catholic aid organizations, and they will be able to advise you on the best way to clothe people. By the way, I have nothing but respect for people who are willing to donate and be active in order to help people they've never met.
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