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Since we're talking about David Gilmour....my favourite solo by him is the Time solo, but that's followed very closely by the intro to Wish You Were Here.
As for others...
Duane Allman doing Statesboro Blues live at Fillmore East...also Whipping Post
Ritchie Blackmore doing Highway Star
Hendrix - Little Wing, Castles Made of Sand, and Red House
Jimmy Page - Hearbreaker and When the Levee Breaks and Bron Y Aur Stomp
BB King - The Thrill Is Gone
Eddie Hazel - Maggot Brain
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