For the long run, I'd have to agree with ryborg, the Struts or Spring frameworks and Java are really nice. I'm kinda partial to Spring and Hibernate (probably cause I have a thing for reflective coding and XML). Looking around on the net you can find tons of examples using Spring and Hibernate, not to mention books about them both (Spring in Action, etc..).
For the short term I would consider LAMP (Linux, Apache, MySQL, PHP) the way to go.
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