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Pink Floyd - Shine On You Crazy Diamond Part 2. The guitar solo (really the entire mid-end section) when he starts getting really high on the frets.
The Who - Won't Get Fooled Again. The opening on the keyboard/synth.
The Tea Party - Sister Awake. The peaceful ballad turns into a middle-eastern rock hybrid. Kicks mucho ass live.
White Zombie - Black Sunshine. "The wheels of his Mustang exploding on the highway like a slug from a .45. True death: 400 horsepower of maximum performance piercing the night... This is black sunshine."
Apocalyptica - Toreador II. The finale where all four cellos are ripping and a trumpet starts playing a Spanish lick.
Dream Theater - A Change of Seasons (Live version). The crowd starts singing the guitar intro.
Jimi Hendrix - Red House. "Hey, my baby don’t love me no more. Lord, I know good and well that her sister will".
Metallica - Orion. Kirk and James' duet into Kirk's solo.
Ozzy Osbourne - Mr. Crowley. Zakk Wylde's solo.
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