Thread: BrainQuest!
View Single Post
Old 01-02-2005, 10:50 PM   #6 (permalink)
ICER
Chilled to Perfection
 
ICER's Avatar
 
Location: Dallas, TX
Well, I found the reason for the boiling point question:

Quote:
Salt (or other solutes, like sugar) can easily dissolve in liquid water. However, taking the solute out of the water and putting it in the gas phase (air) requires a lot of energy. At temperatures around the water boiling point, these solutes stay in the liquid.

Now the total pressure in the liquid and the air at the boundary are the same- otherwise one would push the other into a smaller space. Part of the pressure in the liquid comes from the solutes, not the water. So the pressure due to the water alone is reduced compared to that of pure water at the same temperature. The vapor pressure, that is, the pressure of water vapor that would stay in equilibrium with the liquid, is reduced by the same amount because of the solutes.

Water boils when the vapor pressure of the water gets to be as big as the pressure of the atmosphere. At that point, vapor bubbles in the water can grow. You have to heat the liquid with solutes up more to get the vapor pressure in it to equal the atmospheric pressure, so it has a higher boiling point.

A very similar argument explains why solutes also lower the freezing point. Since the solutes are almost completely excluded from the solid (like from the gas) they stabilize the liquid. A search of this site will turn up some answers about freezing salt water.

http://van.hep.uiuc.edu/van/qa/secti...0912061445.htm
still working on the weight/mass thingy
__________________
What's the difference between congress and a penitentiary?
One is filled with tax evaders, blackmailers and threats to society.
The other is for housing prisoners.
~~David Letterman
ICER is offline  
 

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360