I would say besides the Usual Suspects which basically everyone here has said...
Chinatown had a great twist ending. One of the few films that I actually didn't keep thinking about how much I hated Jack Nicholson the whole time. Also a Roman Polanski film which normally I wouldn't pay a dime to see anything he does. But this movie is great, its a classic, and it has a great twist ending.
Also, I think Se7en was great as far as twist endings go.
I saw the end of the sixth sense coming about halfway through the movie, so I disagree on that one. But a good film nonetheless.
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