I couldn't vote for any because I love all 4 of those bands and they all have a different sound.
Pearl Jam has a really good mellow sound but can also crank it out. I think they're music is pretty sophisticated compared to the other bands listed.
Nirvana's music has more of a punk-ish influence with a lot of screaming, angsty music. Very simple stuff to play.
Soundgarden has power. Chris Cornell belts out notes that peel paint off walls. He beats all the other bands singers in my opinion. Overall, Soundgarden has a rock-and-roll feel.
Alice in Chains is a darker band. Layne Stanley had a voice that let you know this. I'd say their music was a mix of angst and depressing (but not depressing in a bad way... if you know what I mean).
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