Go to the "Control Panel", choose "Set Program Access and Defaults", click on "Custom", look for the "Choose a default e-mail program" and select a program other than "Outlook Express".
If you want mail links to go directly to your GMail account, I believe that you may need to have the GMail notifier installed. If you do have it installed, right-click on it, select "Options" and check the box that says, "Use GMail for internet mailto: links".
Hope this helps.
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