Try widening your grip. If you want to hit the pec's almost solely, you want your hands as wide on the bar as you can make it.
Usually I do 3 reps of regular (about one inch past shoulder-width), 2 tight grip (about 2inches from hand-to-hand), and 2 wide grip (hands all the way to the ends of the bar).
You can do the same for pushups with wide/tight grip. Also I suggest doing decline press, it works out the bottom half of your pecs and gives them a nice lift.
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