I'd have to say that Voodoo Chile's intro is one of my all time favorites.
The others would have to include:
Little Wing (Hendrix or SRV)
Yellow Ledbetter (Pearl Jam)
Alive (Pearl Jam)
Layla (Derek and the Dominoes)
Black Dog (Zep)
Obviously the best riffs in all of those would be the intros.
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"The power of accurate observation is frequently called cynicism by those who don't have it." - George Bernard Shaw
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