If you want to compare Goku before he was resurrected the first time with Superman, Superman would win. I mean, Supes eats guys like Raditz for breakfast. He wouldn't have any chance against Goku after he came back, though.
My favorite villain is Frieza, personally. He was completely, unrepentantly evil. Even if it was around his time that the show started all that stalling and the episode-long yelling sessions... longest five minutes I ever saw. The pacing of the manga never had any problems, in comparison.
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Killing that robot makes me want to go home.
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