I just bought it today for PS2, and let me just say this: I spent literally over 3 HOURS just webbing around beating thugs up and roaming. The webslinging definitely puts you in mind of the movies, with all sorts of insane, over-the-top moments that just make you think: "hey...this kicks some ass". The combat can be a little iffy, mostly devolving into button mashing. But if you can master some of the more intracate combos and moves it's very rewarding. The only reason I stopped playing was because I didn't want to go too far into the storyline untill I saw the movie. But I definitely recommend it to any Spider-Man fans, and maybe everyone else too.
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