On the alley-- I'm sure it's been used many, many times. But I specifically remember it being in the very first episode. The camera pans over the bar or whatever that Buffy jumped up to and balanced on when she wanted to find out who was following her (Angel, of course.)
What's next, t3m3st? 
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"...for though she was ordinary, she possessed health, wit, courage, charm, and cheerfulness. But because she was not beautiful, no one ever seemed to notice these other qualities, which is so often the way of the world."
"Tell me, what is it you plan to do with your one wild and precious life?"
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