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I think there are more then one server, I also think that there are multiple ports that AIM uses. I think there are two other ones, and then it resorts to port 80, so blocking the port is prollay out of the idea.
What kind of computers are you using at work?
If it's anything new, I bet you could just disable it. Or implement a rule that if you're found to be using it, poop will fly?
No matter how hard you try to disable something, people will find a way, so make rules with punishments and let everyone know them.
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