the trouble with dating your friends sister (for a physical relationship) is this might alienate your friend. have you considered how he might react to such a relationship? And a physical relationship sounds like it wouldn't be all that serious. Do you think she would be interested in a relationship with little emotional investment? Do you think your friend would appreciate you having a merely physical relationship with her?
As for the girl at work, from the little information I have the only problem I forsee is a conflict of religious beliefs, but unless either of you are very adamant about your beliefs, this shouldn't be too big a problem. Also from what you've said, I'm guessing this girl might not be as attractive as your friend's sister, but that's a matter of taste.
I recommend nothing, but agree that you shouldn't make a move on either until you've committed to a plan of action.
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