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I agree with collide.
1. Butch: technically there's a flashback to his childhood so that makes him first. Adult Butch first appears after the Wolf when he sizes up Vincent in Marsellus's place.
2. Marvin: Shot in the car.
3. Mia: Seen by the poolside when Marsellus says he's sending the Wolf.
3. The Wolf: Called in because of the goo formerly known as Marvin.
4. The Gimp: The whole Butch storyline takes place a few days after the adventures of Jules, Vincent & Mia.
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