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If you want speeding tickets, play the William Tell Overture.
Otherwise, all of Bach's Brandenburg Concertos are awesome.
Mozart's symphony #40 (Jupiter), Abduction from the Seraglio, Turkish Rondo, Requiem, clarinet concerto, french horn concerto, oboe concerto, and bassoon concerto.
Pachelbel's Canon in D
Vivaldi's 4 seasons (you'll recognize all of these - they're used a LOT)
Handel's Water Music (really cool)
Buddyhawks is right - anything played by Yo Yo Ma is really cool. He did an album with Bobby McFerrin - Hush - that's kinda neat.
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