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Stiltzkin 12-01-2004 10:18 PM

PLEASE HELP!
 
I need an answer to this quick, quick, quick. Well moreso, an explanation of how to solve it, because I have the answer.

From the following heats of combustion,
CH<sub>3</sub>OH<sub>(l)</sub> + 3/2O<sub>2(g)</sub> --> CO<sub>2(g)</sub> + 2H<sub>2</sub>O<sub>(l)</sub> enthalpy of reaction=-726.4 KJ/mol
C<sub>(graphite)</sub> + O<sub>2(g)</sub> --> CO<sub>2(g)</sub> enthalpy of reaction=-393.5 KJ/mol
H<sub>2(g)</sub> + 1/2O<sub>2(g)</sub> --> H<sub>2</sub>O<sub>(l)</sub> enthalpy of reaction=-285.8 KJ/mol

calculate the enthalpy of formation of methanol (CH3OH) from it's elements:
C<sub>(graphite)</sub> + 2H<sub>2(g)</sub> + 1/2O<sub>2(g)</sub> --> CH<sub>3</sub>OH<sub>(l)</sub>

How the heck do I find enthalpy of formation?
I KNOW this is in the wrong board, I know where this type of question belongs, but let's face it, it could take a whole day before anyone sees it.

Please leave this here long enough for someone to help me.

I went to a review session but the TA didn't know how to explain it, she just solved it. She solved it by multiplying the first reaction's enthalpy by (-1) and the third reaction's enthalpy by (2). Afterwards she added up all the enthalpies. The problem is that I don't understand <i>why</i> she did that and she couldn't explain it either >.<

Please help!

Hard8s 12-01-2004 10:45 PM

Check this out.
http://wine1.sb.fsu.edu/chm1045/notes/Energy/HeatForm/Energy05.htm
Hope it helps.

Hard8s 12-01-2004 10:48 PM

here is another link
http://dbhs.wvusd.k12.ca.us/webdocs/...Formation.html

Stiltzkin 12-01-2004 10:59 PM

They didn't help, but I do appreciate the effort. I *think* I got it now, though.

Well, I looked at an example in the book and I worked it through, and it turns out that it's not that hard. The reason why the TA couldn't explain it is because it's kind of a process of trial and error, and she seemed like she was in a hurry.

I apologize for the out-of-context-ness of this post, though. Feel free to move it to the appropriate board now.

Hard8s 12-01-2004 11:01 PM

Moogle on then my brother!! Moogle on.


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