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Probably place the OS drive on channel 0 as master (with out slave present) and on channel 1, the new hard drive as master and the optical as slave.
Drive letters should be no problem, when you add the drive, it will not be formatted, and hence not have a drive letter. After windows boots, initialize the disk, add a partition, format it (full format, don’t do the half ass quick format) then give it a drive letter.
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