Condolences about your niece - what a horrible loss.
Given that you have described yourself as not being close to the woman, I don't think there is anything you can do to help her - unless you are close to someone with whom she is close and can communicate via them. People with substance abuse problems, however, generally won't listen unless they see that they will lose something they value by continuing their behavior. It's awful to be in a helpless situation - but realistically, I think that is where you are regarding this woman.
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