Well, I'd also add the Varsity in Atlanta if you're going through. I see you adopted that filthy ratbastid's idea to skip Columbia and hit straight from Atlanta to Greenville. This means you'll miss out on mustard-based BBQ in SC, which is mostly a mid-state thing. Upstate means you can get some catsup-based bbq, and maybe some mustard. In Greenville, I'd recommend Henry's Smokehouse - and if you cut over to Spartanburg (45 miles from Greenville), you can hit the Beacon. Much better known. Not necessarily a BBQ place, although people in the area love their catsup-based hash. It's got great greasy cheeseburgers, and is sort of a local legend.
Personally, I'm more of a pepper-vinegar guy myself, but the best of that would take you closer to the coast. There are some pretty decent places on your original route via I-20 in the Aiken/Augusta region. However, rb is right that 85 will save you a pretty good bit of time.
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