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There is a very good chance the ram won't work with it.
1. That CPU is old so the motherboard must be old also. The motherboard may take a RAM format previous to DDR ram so it would have a different amount of pins and wouldn't even fit.
2. The ram you listed is DDR-400, the fastest DDR ram available before it was outdated. That Pentium 4 definitely does not take DDR-400 ram. The ram you listed would be way too fast for the motherboard and CPU and probably wouldn't even boot up.
If you can tell us the motherboard or serial number/service tag of the PC we can find out more about it and link some ram that would work.
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