I wouldn't rule out a yeast infection, you'd be surprised how they manifest sometimes. It could definately be a sensitivity to the latex, or it could be irritation from a change in your ph balance after sex. I had this issue for a while because we weren't using condoms and my boyfriend's semen irritated the area. It manifested as burning mostly but that was right after sex.
I would expirement with different types of condoms so that you can see how different materials make a difference. Oh yeah, and definately see a doctor.
Edit: I've used the Vagisil wipes before, they work pretty well to keep the itching and burning under control. You might want to try them.
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