Arrested Development
Invader Zim - Moderately subversive for something that originally aired on nickelodeon
Nova - don't know if there are dvd's available, but you could probably make your own
How It's Made - This show is basically just narrated footage of the manufacturing processess of various everday things. The engineer in me finds it pretty interesting, not sure if you would because you might not be a dork like that.
Lost - is seconded
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